Well, i got my WoMT in the mail, and I looke dup a bunch of painting guides for them. However, whenever I do the black detailing wash, it ends up looking splotchy, and the second silver coat has spots of black everywhere except for where I want them. Does anyone have any advice?

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Use oil paints and mineral spirits. Check out this link. http://www.missing-lynx.com/rare_world/rw04.htm If you don't want oils in your house, then apply a gloss or semigloss coat before the wash, so it'll flow better.

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Also be careful when you are applying it. If you apply too much wash gravity will draw the wash out of the recesses where you want it and make a mess of your armour. Also, always leave several hours before and after you apply a wash. When in doubt, wait a little longer. It always works best when the surface is completely dry.